Jaycar or Ebay will sell calibration fluids.
find a solution as close to natural salt water as you can (53ms), then use a conversion chart off google to get a specific gravity based on the solution you brought.
Accurasea is a great product off the shelf at many LFS. it is just purified natural salt water, but if you treat it like a check for a million dollars it should last a few years. and is 1.026
RO, even RODI wont give you accuracy. think of the speedo in your car, most are spot on at 60km, but out by a little at 110km. best to calibrate to a number close to what it will be testing.
Melbourne sea water can vary a little in the bay, but is generally 1.028 on a high tide at Mornington.
another simple way that will be find-able on google somewhere as my head hurts from a long day, so math is out of the question.
using artificial salt water, X grams per liter = (specific gravity). randy made his own versions too.
like ALL parameters STABILITY is number 1!
Tip. although most refractometers are ATC, auto temp compensating. float your test solution in the tank for 5 minutes. that way you will calibrate the refractometer at the same temp as the water that will be tested.